Contact Info

Adam P. Hitchcock

Canada Research Chair

in Materials Research
CLS-CCRS
B.I.M.R
McMaster University
Hamilton, ON
Canada L8S 4M1
V: +1 905 525-9140
    x24729
F: +1 905 521-2773
E: aph@mcmaster.ca
U: unicorn.mcmaster.ca
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X-ray patterning with 30 nm resolution

WHO:  Adam Leontowich, Adam Hitchcock, Harald Stover
            Chemistry & BIMR, McMaster University

WHERE:  ALS Scanning Transmission X-ray Microscope (STXM) 5.3.2
 
WHEN:   June 2009                        POSTED:  30 Sep 2009

WHAT: Low dose & chemical development shows STXM-based patterning achieves 30 nm resolution

The PhD thesis research of Jian Wang showed that tunable synchrotron light focused in a STXM can generate chemically selective patterns in multi-layer polymer structures [1,2]. However , the spatial resolution achieved was 150 nm or worse, due to radiation damage spreading and the need to use high doses to have sufficient contrast for STXM analysis. Adam Leontowich has found if patterns are generated by STXM and then chemically developed, much higher spatial resolution can be achieved - but the development is not actually needed to show high resolution. The figure shows an AFM image (Quescant 350) of a 10x10 shot damage pad burned into a 40 nm thin film of PMMA using a dose of 120 MGy (200 ms @ 11 MHz, 300eV) - prior to chemical development. Each individual damage exposure (30 ms) is visualized. With appropriate methodology patterns with features as sharp as the known spatial resolution of STXM (30 nm) can be made.

OTHER INFORMATION: Chemically selective patterning has been described in:
1. J. Wang, H.D.H. Stöver, A.P. Hitchcock and T. Tyliszczak. Chemically selective soft X-ray patterning of polymers, J. Synchrotron Radiation 14 (2007) 181
2. J. Wang, H.D.H. Stöver and A.P. Hitchcock, Chemically selective soft X-ray direct-write patterning of multilayer polymer films, J. Phys. Chem. C 111 (2007) 16330

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